Cluster Sliding Ferroelectricity in Trilayer Quasi-Hexagonal C60
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Electric polarization typically originates from non-centrosymmetric charge distributions. Since chemical bonds between atoms of the same elements favor centrosymmetric crystal structures and symmetrically distributed electron charges, elemental ferroelectrics are extremely rare. In comparison to atoms, elemental clusters are less symmetric and typically have various preferred orientations in crystals. Consequently, the assembly of clusters with different orientations tends to break the inversion symmetry. Based on this concept, we show that sliding ferroelectricity naturally emerges in trilayer quasi-hexagonal phase (qHP) C 60 , a cluster-assembled carbon allotrope recently synthesized. Trilayer qHP C 60 ’s have several ferroelectric structures, which are distinguishable in second-harmonic generation (SHG) responses. Compared to previously found elemental ferroelectrics, trilayer qHP C 60 ’s have sizable band gaps and some of them have both switchable out-of-plane and in-plane polarizations. The out-of-plane and in-plane polarizations of these trilayer systems can be switched independently and enable an easy-to-implement construction of Van der Waals homostructures with ferroelectrically switchable chirality.