Photoresponsive TiO2/Graphene Hybrid Electrodes for Dual-Function Supercapacitors with Integrated Environmental Sensing Capabilities

This review critically examines photoresponsive supercapacitors based on TiO2/graphene hybrids, with a particular focus on their emerging dual role as energy-storage devices and environmental sensors. We first provide a concise overview of the electronic structure of TiO2 and the key attributes of graphene and related nanocarbons that enable efficient charge separation, transport, and interfacial engineering. We then summarize and compare reported device architectures and electrode designs, highlighting how morphology, graphene integration strategies, and illumination conditions govern specific capacitance, cycling stability, rate capability, and light-induced enhancement in performance. Particular attention is given to the underlying mechanisms of photo-induced capacitance enhancement—including photocarrier generation, interfacial polarization, and photodoping—and to how these processes can be exploited to embed sensing functionality in working supercapacitors. We review representative studies in which TiO2/graphene systems operate as capacitive sensors for humidity, gases, and volatile organic compounds, emphasizing quantitative figures of merit such as sensitivity, response/recovery times, and stability under repeated cycling. Finally, we outline current challenges in materials integration, device reliability, and benchmarking, and propose future research directions toward scalable, multifunctional TiO2/graphene platforms for self-powered and environmentally aware electronics. This work is intended as a state-of-the-art summary and critical guide for researchers developing next-generation photoresponsive supercapacitors with integrated sensing capability.