HAT-Initiated Fragmentation of Alkene-Tethered Enaminone

  1. Andrej Bogataj
  2. Luka Ciber
  3. Nejc Petek
  4. Franc Požgan
  5. Jurij Svete
  6. Bogdan Štefane
  7. Uroš Grošelj
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Abstract

An alkene-tethered enaminone was synthesized in four steps from bromoacetic acid and 3,3-dimethylallyl alcohol. The enaminone was fully characterized, including UV-Vis spectra. TBADT-catalyzed HAT of the alkene-tethered enaminone initiated a fragmentation that yielded the literature-known phenylacetone-derived enaminone.

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  1. Version published to 10.20944/preprints202602.0857.v1