Enhancing Perovskite Solar Cell Stability by TCO Layer Presence Beneath MACl-Doped Perovskites

Perovskite solar cells (PSCs) have emerged as a promising photovoltaic technology, yet their stability under environmental stressors remains a critical challenge. This study examines the substrate-dependent degradation mechanisms of perovskite films and evaluates the role of me-thylammonium chloride (MACl) incorporation. Devices fabricated on ITO and glass substrates exhibited markedly different stability behaviors under high-humidity conditions. ITO substrates delayed the phase transition from the black α-phase to the yellow δ-phase due to stronger sub-strate-film interactions and reduced defect densities, while glass substrates facilitated rapid deg-radation through moisture infiltration and grain boundary instability. MACl incorporation en-hanced the initial crystallinity and optoelectronic properties of the perovskite films, as evidenced by superior power conversion efficiency and photon absorption. However, residual MACl under humid conditions introduced structural instability, particularly on glass substrates. To address these challenges, a fully coated ITO structure, referred to as the Island Type design, was proposed. This structure eliminates exposed glass regions, leveraging the stabilizing properties of ITO to suppress moisture infiltration and prolong device durability. The findings provide a compre-hensive understanding of the interplay between substrate properties and material composition in PSC stability and highlight the potential of structural optimizations to balance efficiency and durability for commercial applications.