The Morphology-Controlled Fabrication   of Lanthanum-Based Nanostructures for Advanced Catalytic Applications

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Abstract

The morphology of nanostructures plays a pivotal role in determining catalytic efficiency, surface reactivity, and material stability. Lanthanum-based nanomaterials, including oxides and rare-earth-derived composites, offer exceptional physicochemical properties such as high oxygen mobility, tunable electronic structures, and thermal stability. This study explores the controlled synthesis of lanthanum nanostructures using solution-assisted and thermal methods, highlighting how reaction parameters—precursor concentration, pH, temperature, and calcination conditions—influence shape, crystallinity, and surface area. Resulting morphologies, including nanorods, nanosheets, and hierarchical porous architectures, were achieved systematically. Structural analyses confirmed phase purity and uniform particle distribution, while surface characterization revealed enhanced active-site exposure in anisotropic forms. Catalytic evaluation in representative redox and environmental reactions showed that morphology-driven surface engineering significantly enhances reaction kinetics and long-term stability. Nanorod and porous structures exhibited superior performance due to improved charge transport and higher accessible surface areas. These results underscore the importance of morphology control in designing high-performance lanthanum nanocatalysts and provide a scalable framework for establishing structure–property–performance correlations relevant to environmental and energy applications.

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