Petrology and Geochemistry of Scandium in Wailukum Ni Laterites, East Halmahera, Indonesia

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Abstract

The Wailukum area in North Maluku Province, Indonesia, is an ultramafic rock complex with a high degree of serpentinization. The mineral composition of ultramafic and mafic rocks strongly influences the distribution and enrichment of scandium (Sc) during lateritization. In this study, we aim to analyze three types of geological materials in a lateritic profile that contains Sc, specifically bedrock, saprolite, and limonite, in terms of element distribution, mineral composition, and rock identification. We used the analytical methods of petrography, X-ray diffraction (XRD), X-Ray Fluorescence (XRF), and Inductively Coupled Plasma–Optical Emission Spectroscopy (ICP-OES). The results show that Sc in bedrock is mainly associated with clinopyroxene minerals such as augite and diopside. In saprolite, Sc content decreases due to higher mobility but remains partly associated with clinopyroxene, and in limonite zone, Sc reaches maximum enrichment. Among rock types, gabbro contains the highest absolute Sc concentration (23.25 ppm in bedrock and up to 58.5 ppm in limonite), while wehrlite records the greatest enrichment ratio, with a 9.18-fold increase from bedrock to limonite. By contrast, gabbro shows the lowest enrichment ratio (2.52-fold) despite its high initial Sc content. These patterns indicate that Sc enrichment is controlled by clinopyroxene as the primary host in bedrock, affecting its relative stability during weathering.

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