The efficiency of rare earth doped V 2 O 5 nanoparticles on photocatalytic and antibacterial activity

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Abstract

In this study, V 2 O 5 and La doped V 2 O 5 nanoparticles were synthesized using a hydrothermal method to toxic pollutants removal from wastewater and assess the antibacterial activity. The prepared samples were characterized by sophisticated characterization techniques. XRD confirmed that La doped V 2 O 5 samples exhibit an orthorhombic crystal structure, with the bandgap of La-doped V 2 O 5 nanoparticles being 2.4 eV, which is smaller than V 2 O 5 . The bandgap of La-doped V 2 O 5 nanoparticles was predicted using a popular machine learning algorithm based on XGBoost technology. FE-SEM images of both samples depicted typical platelet and layered like structures, and EDX validated the presence of La, V and O in the La doped V 2 O 5 nanoparticles, verifying the elemental composition. The photocatalytic activity of samples were investigated by the photodegradation of rhodamine B (RhB) under visible light irradiation. In the photocatalytic performance of La doped V 2 O 5 sample exhibited faster decolorization of RhB and higher photodegradation efficiency compared to V 2 O 5 . Furthermore, the potential toxicity of V 2 O 5 and La doped V 2 O 5 samples were investigated using L. acidophilus and S. typhi bacteria. La doped V 2 O 5 nanoparticles improved the charge carrier separation and decreased the rate of recombination which significantly enhanced the photocatalytic and antibacterial activity.

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