Thermalization Dynamics in Open Quantum Systems: Competition Between Hamiltonian Strength and Decoherence Rate

Understanding thermalization and irreversibility in open quantum systems requires char-acterizing the competition between coherent unitary dynamics and dissipative environmen-tal interactions. In this work, we present a systematic numerical study of thermalization dynamics in a two-qubit open quantum system governed by a completely positive and trace-preserving Lindblad master equation. The coherent evolution rate is controlled by a real scaling parameter α multiplying the Hamiltonian commutator, while decoherence is indepen-dently controlled by a dephasing rate γ . Although such a scaling of coherent dynamics can be absorbed into a rescaling of time in isolated systems, it becomes physically meaningful in open systems where decoherence introduces an absolute timescale. We investigate how the relative strength of coherent evolution and decoherence influences observable dynamics, purity decay, entropy production, and thermalization times. Using robust local and two-site observables, we show that varying α at fixed γ produces distinct transient trajectories, even though all evolutions converge to the same steady state. We further define an operational thermalization time τ ( γ, α ) based on a purity threshold and map the resulting thermalization-time surface across a broad parameter range. Increasing α generally accelerates oscillatory dynamics and modifies the approach to equilibrium, leading to measurable shifts in thermalization times without altering asymptotic states. These findings provide a clear and physically consistent characterization of how Hamil-tonian strength and decoherence rate jointly determine thermalization behavior in open quantum systems. The framework offers a practical parameterization for numerical mod-eling and experimental studies of coherent–dissipative competition in quantum information processing, quantum control, and open-system dynamics.