Palladium/phosphoramidite-selenide-catalyzed enantioselective allylic amination

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Abstract

Herein, we report an enantioselective Pd-catalyzed allylic amination reaction using phosphoramidite-selenide ligands. A wide variety of N-nucleophiles are suitable in this reaction, furnishing corresponding allylic amination products up to 93% yield and 90% ee.

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