Multisite atomic-chlorine-passivation stabilizes perovskite interfaces for efficient H2O2 photosynthesis from seawater

Read the full article See related articles

Discuss this preprint

Start a discussion What are Sciety discussions?

Listed in

This article is not in any list yet, why not save it to one of your lists.
Log in to save this article

Abstract

Lead halide perovskites are promising for artificial photosynthesis but suffer from aqueous instability. Here, we stabilize CsPbI 3 quantum dots (QDs) within a hydrophobic chlorine-functionalized covalent organic framework (COF-Cl) through multisite atomic-chlorine passivation, forming dual Cl–Pb coordination and Cl–I halogen bonding at the interface. This suppresses ionic migration while creating a gas–liquid–solid triphase interface for enhanced O 2 diffusion. The resulting S-scheme heterojunction spatially separates carriers to concurrently drive two-electron oxygen reduction and water oxidation for H 2 O 2 synthesis without sacrificial agents. The system achieves record production rates of 25.29 mmol h -1 g -1 in pure water and 20.37 mmol h -1 g -1 in seawater under visible light, with a solar-to-chemical conversion efficiency of 1.38%. Crucially, it operates stably for 20 h in seawater and produces 11.7 mmol L -1 H 2 O 2 in 10 h under natural sunlight. Mechanistic studies confirm synergistic interfacial charge transfer and dual-reaction pathways via both oxygen reduction and water oxidation. This work establishes a paradigm for robust perovskite-based photocatalysts toward scalable solar-driven chemical synthesis from seawater.

Article activity feed