All-in-One van der Waals Material for Light Detection, Guiding and Modulation

Modern optoelectronic devices demand materials that can perform multiple, often conflicting functions, such as acting as metals for interconnects, dielectrics for waveguides, and semiconductors for light emission and detection. The integration of these materials is challenging, slowing industry progress and increasing costs. It inspired an intensive search for a universal optoelectronic response within a single material. Here, we reveal that palladium diselenide (PdSe ₂ ) provides an answer to this quest owing to its unique bandstructure. It exhibits a semimetallic band structure with an unusually large bandgap for interband transitions responsible for semiconductor-metallic nature. This duality enables PdSe ₂ to function as both a photodetector and a waveguide, integrating two traditionally incompatible responses. As a result, our findings provide a full picture of PdSe ₂ optoelectronic properties, paving the way for its use in multifunctional optoelectronic applications in one material.