Hydroxide exchange membrane carbon capture using a nickel hydroxide symmetric battery cell
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Electrochemical carbon capture devices can be a low energy cost solution for direct air capture (DAC) using renewable electricity. Historically electrochemical carbon-capture has targeted a range of concentrations from atmospheric (400 ppm CO2 ) (DAC), 1 to life-support (5000 ppm CO2 ), 2 to point-source capture (10% CO 2 ). 3 The hydroxide exchange membrane nickel hydroxide symmetric battery cell with two identical electrodes has low voltage requirements making it more suitable for DAC than other electrochemical approaches. A 25 cm 2 laboratory cell shows an average energy cost of 1.15 MWh·ton CO2 −1 and a CO 2 flux of 78 kg CO2 ·m 2 ·yr − 1 at 2 mA·cm − 2 . A manufacturable 25 cm 2 cell is durability tested for 5000 hours and achieves an energy of 0.46 MWh·ton CO2 −1 and a flux of 62 kg CO2 ·m 2 ·yr − 1 at the end of the test. A DAC pilot system with a stack of 9 scaled-up 300 cm 2 cells demonstrates an energy of 0.83 MWh·ton CO2 −1 and a flux of 75 kg CO2 ·m 2 ·yr − 1 and meets the 300 Pa pressure drop required for DAC. 4 Modular design projects improvements in cost from manufacturing and economies of scale, and a pathway to below 100 $·ton CO2 −1 from learning rates of past energy technologies. 5