On the Energy Transfer in Bi2WO6: ERedOx Assisted Radiative Recombination in O2 and ROS Sensing. Prospective

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Abstract

Photoluminescence maximum emission signal of colloids based on Bi 2 WO 6 suspended in an aqueous solution is blue-shifted as compared to its band gap according to E g + (E RedOx -E CB ). This process involves the exergonic non-radiative transfer of E CB electron to E RedOx and the concomitant radiative emission of a second electron that has gained E RedOx -E CB energy presumably by electrons energy levels entanglement induced via simultaneous light excitement of multiple electrons. These results constitute evidence for energy transfer with application in sensing electrolyte-electron-acceptors as reactive oxygen species that may be implemented for example in cancer and aortic dissection detection and treatment.

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