Sextuple-Q Spin States in Centrosymmetric Hexagonal Magnets

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Abstract

We theoretically investigate multiple-Q instabilities in centrosymmetric hexagonal magnets, formulated as superpositions of independent six ordering wave vectors related by sixfold rotational and mirror symmetries. By employing a spin model that incorporates biquadratic interactions and an external magnetic field, we establish a comprehensive low-temperature phase diagram hosting single-Q, double-Q, triple-Q, and sextuple-Q states, as well as skyrmion crystals with topological charges of one and two. The field evolution of the magnetization, scalar spin chirality, and finite wave-vector magnetic amplitudes reveals a hierarchical buildup of multiple-Q order, accompanied by first-order transitions between topologically distinct and trivial phases. At large biquadratic coupling, all six symmetry-related ordering wave vectors coherently participate, giving rise to two sextuple-Q states under magnetic fields and to another spontaneous sextuple-Q state even at zero field. The latter zero-field sextuple-Q state represents a fully developed sixfold interference pattern stabilized solely by the biquadratic interaction, characterized by alternating skyrmion- and antiskyrmion-like cores with vanishing uniform scalar spin chirality. These findings establish a unified framework for understanding hierarchical multiple-Q ordering and demonstrate that the interplay between bilinear and biquadratic interactions under hexagonal symmetry provides a generic route to complex noncoplanar magnetism in centrosymmetric itinerant systems.

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