Enhancing the Selectivity of Nitroso-R-Sal for the Determination of Co(II) in Lithium Bioleaching Recovery of Smartphone Batteries Using a Combinatorial Methodology Approach

The selectivity of the colorimetric method for Co(II) determination using the nitroso-R-salt (NRS) in samples with complex matrix had been improved. Interferences caused by Cu(II), Fe(II), Fe(III), Mn(II), Al(III) and Ni(II) ions, which were present in the bioleachate of lithium-ion batteries, have been solved through the sequential addition of masking agents: acetate, fluoride, ethylenediaminetetraacetic acid (EDTA), and strong acids (H2SO4). The absorbance of the NRS-Co(II) complex was typically measured at 525 nm but it was also studied at 550 nm due to minimal interferences observed at 550 nm. The sequence of the masking agent’s addition showed a significant influence on the interferences effect. The optimal sequence was sample, acetate-acetic acid buffer solution with dissolved fluoride, NRS, EDTA and H2SO4. The proposed method demonstrated robust performance at 550 nm, with a relative standard deviation (RSD) around 2%, accuracy (RV% around 100%). The limit of detection (LoD) was 0.1 mg L-1 and the limit of quantification (LoQ) was 0.3 mg L-1. The linear range extended up to 15 mg L-1 (R2= 0.998). Real samples analyzed using the optimized method showed no significant differences when compared to results from atomic absorption spectroscopy, confirming its reliability.