Design, Build and Testing of a Portable Methane Measurement Platform

The quantification of methane concentrations in air is essential for the quantification of methane emissions, which in turn is necessary to determine absolute emission and the efficacy of emission mitigation strategies. These are essential if countries are to meet climate goals. Large scale deployment of methane analyzers across the millions of emission sites is prohibitively expensive and lower-cost instrumentation has been recently developed as an alternative. Currently, it is unclear how cheaper instrumentation will affect measurement resolution or accuracy. To test this, the Wireless Autonomous Transportable Methane Emission Reporting System (WATCH4ERS) has been developed and comprises four sensing technologies: Metal Oxide (MOx,); Non-dispersion Infrared (NDIR); Integrated Infrared (INIR); and Tunable Diode Laser Absorption Spectrometer (TDLAS). This study describes the integration of these sensors to a single unit and test instrument response through calibration and downwind tests. Both calibration and response experiments indicate the INIR has little practical use for measuring methane concentrations less than 500 ppm. The MOx sensor is shown to have a logarithmic response to methane concentration change between background and 600 ppm but it is strongly suggested that passively sampling MOx sensor cannot respond fast enough to report concentrations that change on a sub-minute time frame. The NDIR sensor reported linear change to methane concentration between background and 600 ppm, although there was a noticeable lag in reporting changing concentration especially at higher values, and individual peaks could be observed throughout the experiment even when the plumes were released 5 s apart. The TDLAS sensor re-ported all changes in concentration but remains prohibitively expensive. Our findings suggest that each sensor technology could be optimized by either operational design or deployment location to quantify methane emissions and the WATCH4ERS units will be deployed in real-world environments to investigate the utility of each in the future.