Preparation of Glass-Ceramic Materials by Controlled Crystallization of Eu<sub>2</sub>O<sub>3</sub> Doped WO<sub>3</sub>-B<sub>2</sub>O<sub>3</sub>-La<sub>2</sub>O<sub>3</sub> Glasses and Their Luminescent Properties

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Abstract

In this paper, the crystallization behavior of 52WO3:22B2O3:26La2O3:0.5Eu2О3 glass has been investigated in detail by XRD and TEM analysis. The luminescent properties of the resulting glass-ceramics were also investigated. By XRD and TEM analysis, crystallization of &beta;-La2W2O9 and La2WO6 crystalline phases has been proved. Photoluminescent spectra showed increased emission in the resulting glass-ceramic samples compared to the parent glass sample due to higher asymmetry of Eu3+ ions in the obtained crystalline phases. It was established that the optimum emission intensity is registered for glass-ceramic samples obtained after 18 h heat treatment of the parent glass.

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